Complexation of 5,5,7,12,12,14-Hexamethyl-1,4,8,11-Tetraazayclotetradeca-7,14-Dienium Bromide With Copper Acetate In Methanol And Aqueous Solutions

Pengkompleksan 5,5,7,12,12,14-heksametil-1,4,8,11-tetraazasiklotetradeka-7,14-dienium bromida dengan kuprum asetat dalam metanol dan larutan berair

  • Bohari M. Yamin School of Chemical Sciences and Food Technology, Faculty of Sciences and Technology, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor Malaysia
  • Aisyah Kadir School of Chemical Sciences and Food Technology, Faculty of Sciences and Technology, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor Malaysia
  • Siti F. M. Yusoff School of Chemical Sciences and Food Technology, Faculty of Sciences and Technology, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor Malaysia
DOI: https://doi.org/10.30598/ijcr.2015.2-boh
Keywords: Tetraaza, complexes, protonated , complexation, kinetics

Abstract

5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclodeca-7,14-dienium bromide disolvate                       ((Me6N4H4)Br2.2H2O) is a 14-membered deprotonated tetraaza macrocyclic salt. Its neutral analogues and their complexes were prepared by templation method under refluxed condition since it was discovered by Curtis in 1961. However, the present diprotonated  tetraaza salts react with many metallic salts in both methanolic and aqueous solutions. The complexation involved deprotonation of the diagonally opposite protonated amines and the type of metal salt and solvents also play an important role in the final complex formation. The complexation of (Me6N4H4)Br2.2H2O with copper acetate in methanol and aqueous solutions gave the expected complex of  [Cu((Me6N4H2)Br]Br.2H2O. Pseudo-first order condition for the complexation reaction in water was established.

Downloads

Download data is not yet available.
Published
2015-01-31
How to Cite
(1)
Yamin, B.; Kadir, A.; Yusoff, S. Complexation of 5,5,7,12,12,14-Hexamethyl-1,4,8,11-Tetraazayclotetradeca-7,14-Dienium Bromide With Copper Acetate In Methanol And Aqueous Solutions. Indo. J. Chem. Res. 2015, 2, 171-175.
Issue
Vol 2 No 2 (2015): Edisi Bulan Januari (Edition For January)
Section
Short communication

Authors who publish with this journal agree to the following terms:

  1. Copyright on any article is retained by the author(s).
  2. The author grants the journal, the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work’s authorship and initial publication in this journal.
  3. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
  4. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.
  5. The article and any associated published material is distributed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.