Synthesis of Glucopyranosyl Acetic from Sago Flour as Raw Material for the Synthetic Polymers

  • Arniah Dali Department of Chemistry Education of FKIP UHO in Kendari
  • Nasriadi Dali Department of Chemistry of FMIPA UHO in Kendari https://orcid.org/0000-0003-4083-3747
  • Seniwati Dali Department of Chemistry, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Jl. Perintis Kemerdekaan Km.10 Tamalanrea, Makassar 90245
  • Hilda Ayu Melvi Amalia Study Program of Tadris Biology, Faculty of Tarbiyah and Teacher Training, Institut Agama Islam Negeri, Jl. Sultan Qaimuddin No. 17, Kendari 93563
DOI: https://doi.org/10.30598//ijcr.2021.8-dal
Keywords: Synthesis, glucopyranosyl acetic, sago flour, hydrolysis, esterification

Abstract

Synthesis of glucopyranosyl acetic from sago flour as raw material for the synthetic polymers has been successfully carried out. The synthesis product is obtained through two reaction stages, namely the hydrolysis and esterification reactions. Sago flour is hydrolyzed with 25% HCl and neutralized with 45% NaOH. Glucose hydrolysis of sago starch and acetic anhydride was esterified using a zinc chloride catalyst. Synthesis product was obtained as a white solid substance (57.31% recovery), a melting point of 110 - 111oC, and Rf 0.79 on TLC (SiO2, n-hexane: ethyl acetate = 9:1 v/v). The results of the analysis of synthesis products with FTIR and GC-MS spectrometers showed that the synthesis product was glucopyranosyl acetic or 2,3,4,6-tetra-O-acetyl glucopyranose.

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Published
2021-01-12
How to Cite
(1)
Dali, A.; Dali, N.; Dali, S.; Amalia, H. Synthesis of Glucopyranosyl Acetic from Sago Flour As Raw Material for the Synthetic Polymers. Indo. J. Chem. Res. 2021, 8, 172-179.
Issue
Vol 8 No 3 (2021): Edition for January 2021
Section
Research articles

Copyright (c) 2021 Arniah Dali, Nasriadi Dali, Seniwati Dali, Hilda Ayu Melvi Amalia

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