Pengaruh Heat Moisture Treatment Menggunakan Microwave dengan Penambahan Gliserol Terhadap Karakteristik Fisikokimia Tapioka

The Effect of Heat Moisture Treatment Using a Microwave with the Addition of Glycerol on the Physicochemical Characteristics of Tapioca

  • Rudi Kelirey Jurusan Teknologi Hasil Pertanian, Fakultas Pertanian, Universitas Pattimura, Jl. Ir. M. Putuhena, Kampus Poka, Ambon 97234 Indonesia
  • Febby J Polnaya Jurusan Teknologi Hasil Pertanian, Fakultas Pertanian, Universitas Pattimura, Jl. Ir. M. Putuhena, Kampus Poka, Ambon 97234 Indonesia http://orcid.org/0000-0002-7750-478X
  • Syane Palijama Jurusan Teknologi Hasil Pertanian, Fakultas Pertanian, Universitas Pattimura, Jl. Ir. M. Putuhena, Kampus Poka, Ambon 97234 Indonesia
Keywords: Heat–moisture treatment, Glycerol concentration, Microwave modification, Physicochemical properties, Tapioca starch

Abstract

This study investigated the effect of glycerol concentration on the physicochemical properties of tapioca starch modified through heat–moisture treatment (HMT) using microwave heating. Glycerol was incorporated at concentrations of 5% (HMTg5), 10% (HMTg10), and 15% (HMTg15) based on the dry weight of tapioca starch, with conventional HMT-modified starch serving as the control. The experiment was conducted using a completely randomized design with a non-factorial structure. The analyzed physicochemical parameters included ash content, water absorption capacity, oil absorption capacity, swelling power, solubility, bulk density, and whiteness index. The results revealed that the water and oil absorption capacities of HMTg starches were significantly higher than those of the control HMT starch. In contrast, ash content, swelling power, solubility, bulk density, and whiteness index decreased with increasing glycerol concentration. These findings suggest that incorporating glycerol during HMT modification alters the starch granule structure and intermolecular interactions, resulting in improved water and oil affinity while reducing swelling and solubility. The modified starches produced in this study demonstrate promising potential for food processing applications and as functional ingredients in biodegradable polymer formulations.

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References

Adebowale, K.O., Henle, T., Schwarzenbolz, U., & Doert, T. (2009). Modification and properties of African yam bean (Sphenostylis stenocarpa Hochst. ex A. Rich.) Harms starch I: Heat moisture treatments and annealing. Food Hydrocolloids, 23(7), 1947–1957. https://doi.org/10.1016/j.foodhyd.2009.01.002

Ajiya, D.A., Jikan, S.S., Talip, B.H., Badarulzaman, N.A., Matias-PeraltaH., M., Derawi, D., & Yahaya, S. (2017). The influence of glycerol on mechanical, thermal and morphological properties of thermoplastic tapioca starch film. Journal of Science and Technology, 9.

Akpa, J.G. & Dagde, K.K. (2012). Modification of cassava starch for industrial uses. International Journal of Engineering and Technology, 2(6), 913–919.

AOAC International. (2012). Official methods of analysis of the Association of Analytical Chemists (19th ed.). AOAC International.

Amaraweera, S.M., Gunathilake, C., Gunawardene, O.H.P., Fernando, N.M.L., Wanninayaka, D.B., Dassanayake, R.S., Rajapaksha, S.M., Manamperi, A., Fernando, C.A.N., Kulatunga, A.K., & Manipura, A. (2021). Development of starch-based materials using current modification techniques and their applications: A review. Molecules, 26, 6880. https://doi.org/ 10.3390/molecules26226880

Ayele, E., Urga, K., & Chandravanshi, B. S. (2015) Effect of cooking temperature on mineral content and anti-nutritional factors of yam and taro grown in Southern Ethiopia. International Journal of Food Engineering, 11(3), 371-382. https://doi.org/10.1515/ijfe-2014-0264

Basiak, E., Lenart, A., & Debeaufort, F. (2018). How glycerol and water contents affect the structural and functional properties of starch-based edible films. Polymers, 10(4), 412. https://doi.org/10.3390/polym10040412

Chen, X., Guo, L., Du, X., Chen, P., Ji, Y., Hao, H., & Xu, X. (2017). Investigation of glycerol concentration on corn starch morphologies and gelatinization behaviours during heat treatment. Carbohydrate Polymers, 176, 56-64. https://doi.org/10.1016/j.carbpol.2017.08.062

Cozar, O., Cioica, N., Coța, C., Nagy, E., & Fechete, R. (2017). Plasticizers effect on native biodegradable package materials. AIP Conference Proceedings, 1796, 040008 (2017) https://doi.org/10.1063/1.4972386

Drouzas, A.E., Tsami, E., & Saravacos, G.D. (1999). Microwave/vacuum drying of model fruit gels. Journal of Food Engineering, 39(2), 117–122. https://doi.org/10.1016/S0260-8774(98)00133-2

Gunaratne, A., & Hoover, R. (2002). Effect of heat–moisture treatment on the structure and physicochemical properties of tuber and root starches. Carbohydrate Polymers, 49(4), 425–437. https://doi.org/10.1016/S0144-8617(01)00354-X

Guo, Y., Xu, T., Li, N., Cheng, Q., Qiao, D., Zhang, B., Zhao, S.-m., Huang, Q., & Lin, Q. (2019). Supramolecular structure and pasting/digestion behaviors of rice starches following concurrent microwave and heat moisture treatment. International Journal of Biological Macromolecules, 135, 437-444. https://doi.org/10.1016/j.ijbiomac.2019.05.189

Hartanto, D. (2012). Kimia Pangan. Yogyakarta: Deepublish.

Juansang, J., Puncha-Arnon, S., Uttapap, D., Puttanlek, C., Rungsardthong, V., & Watcharatewinkul, Y. (2016). Concentration of plasticizers applied during heat–moisture treatment affects properties of modified canna starch. Food Chemistry, 221, 1587–1594. https://doi.org/10.1016/j.foodchem.2016.10.134

Khalil. (1999). Pengaruh kandungan aair dan ukuran partikel terhadap perubahan perilaku fisik bahan pakan lokal: Kerapatan tumpukan, kerapatan pemadatan dan bobot jenis. Media Peternakan, 22(1), 1-11.

Kim, C., & Huber, K. C. (2013). Corn starch granules with enhanced load-carrying capacity via citric acid treatment. Carbohydrate Polymers, 91(1), 39-47. https://doi.org/10.1016/j.carbpol.2012.07.049

Kusnandar, F. (2010). Teknologi Modifikasi Pati dan Aplikasinya di Industri Pangan. Institut Pertanian Bogor. Bogor.

Lazou, A., & Krokida, M. (2010). Functional properties of corn and corn–lentil extrudates. Food Research International, 43(2), 609–616. https://doi.org/10.1016/j.foodres.2009.09.017

Li, J., & Yeh, A. I. (2014). Relationships between thermal, rheological characteristics and swelling power for various starches. Journal of Food Engineering, 50(3), 141-148. https://doi.org/10.1016/S0260-8774(00)00236-3

Nafi, A., Diniyah, N., & Hastuti, F. T. (2015). Karakteristik fisikokimia dan fungsional teknis tepung koro kratok (Phaseolus lunatus L.) termodifikasi yang diproduksi secara fermentasi spontan. Jurnal Agrointek, 9(1), 24–32.

Olayinka, O. O., Adebowale, K. O., & Olu-Owolabi, B. I. (2008). Effect of heat–moisture treatment on physicochemical properties of white sorghum starch. Food Hydrocolloids, 22(2), 225–230. https://doi.org/10.1016/j.foodhyd.2006.11.004

Pająk, P., Madej, M., & Krystyjan, M. (2013). Edible coatings as an alternative to synthetic films. Potravinarstvo, 7(Special Issue), 200-203.

Parwiyanti, P., Pratama, F., Wijaya, A., Malahayati, N., & Lidiasari, E. (2016). Sifat fisik pati ganyong (Canna edulis Kerr.) termodifikasi dan penambahan gum xanthan untuk rerotian. Agritech, 36(3), 335–343. https://doi.org/10.22146/agritech.16606

Picauly, P., Damamain, E., & Polnaya, F. J. (2017). Karakteristik fisiko-kimia dan fungsional pati sagu ihur termodifikasi dengan heat moisture treatment. Jurnal Teknologi dan Industri Pangan, 28(1), 70–77. https://doi.org/10.6066/jtip.2017.28.1.70

Polnaya, F.J. (2020). Amylose Inclusion Complexes. In: Amylose: Properties, Structure and Functions. Himjyoti Dutta, Sanjib Kr. Paul (Editors). Nova Science Publishers, New York.

Sasaki, T., & Matsuki, J. (1998). Effect of wheat starch structure on swelling power. Cereal Chemistry, 75(4), 525–529. https://doi.org/10.1094/CCHEM.1998.75.4.525

Shimamura, T. & Ukeda, H. (2012). Maillard reaction in milk - effect of heat treatment. In: Hurley, W.L. (Ed.). Milk Protein. InTech Open. http://dx.doi.org/10.5772/50079

Srichuwong, S. (2005). Starches from different botanical sources II: Contribution of starch structure to swelling and pasting properties. Carbohydrate Polymers, 62(1), 25–34. https://doi.org/10.1016/j.carbpol.2005.07.003

Sulistyoningsih, M., Rakhmawati, R., & Setyaningrum, A. (2019). Kandungan karbohidrat dan kadar abu pada berbagai olahan lele mutiara (Clarias gariepinus B). Jurnal Ilmiah Teknosains, 5(1), 41-46.

Suriani, A. I. (2008). Mempelajari Pengaruh Pemanasan Dan Pendinginan Berulang Terhadap Karakteristik Sifat Fisik Dan Fungsional Pati Garut (Marantha arundinacea) termodifikasi [Skripsi, Institut Pertanian Bogor].

Tarique, J., Sapuan, S. M., & Khalina, A. (2021). Effect of glycerol plasticizer loading on the physical, mechanical, thermal, and barrier properties of arrowroot (Maranta arundinacea) starch biopolymers. Scientific Reports, 11, 13900. https://doi.org/10.1038/s41598-021-93094-y

Thy, P., Yu, C., Jenkins, B. M., & Lesher, C. E. (2013). Inorganic composition and environmental impact of biomass feedstock. Energy Fuels, 27, 3969-3987. https://doi.org/10.1021/ef400660u

Uzizerimana, F., Dang, K., Yang, Q., Hossain, Md. S., Gao, S., Bahati, P., Mugiraneza, N. G., Yang, P., & Feng, B. (2021). Physicochemical properties and in vitro digestibility of tartary buckwheat starch modified by heat moisture treatment: A comparative study. NFS Journal, 25, 12-20. https://doi.org/10.1016/j.nfs.2021.09.001

Virág, L., Bocsi, R., & Pethő, D. (2022). Adsorption properties of essential oils on polylactic acid microparticles of different sizes. Materials, 15, 6602. https://doi.org/10.3390/ ma15196602

Wang, Y., McClements, D. J., Long, J., Qiu, C., Sang, S., Chen, L., Xu, Z., & Jin, Z. (2022). Structural transformation and oil absorption of starches with different crystal types during frying. Food Chemistry, 390, 133115. https://doi.org/10.1016/j.foodchem.2022.133115

Wang, S., Chao, C., Cai, J., Niu, B., Copeland, L., & Wang, S. (2020). Starch–lipid and starch–lipid–protein complexes: A comprehensive review. Comprehensive Reviews in Food Science and Food Safety, 19(3), 1-24. https://doi.org/10.1111/1541-4337.12550

Zhang, S., Li, Q., Zhao, Y., Qin, Z., Zheng, M., Liu, H., & Liu, J. (2022). Preparation and characterization of low oil absorption corn starch by ultrasonic combined with freeze–thaw treatment. Food Chemistry: X, 15, 100410. https://doi.org/10.1016/j.fochx.2022.100410

Published
2025-10-26
How to Cite
Kelirey, R., Polnaya, F. J., & Palijama, S. (2025). Pengaruh Heat Moisture Treatment Menggunakan Microwave dengan Penambahan Gliserol Terhadap Karakteristik Fisikokimia Tapioka. Jurnal Agrosilvopasture-Tech, 4(2), 189-199. https://doi.org/10.30598/j.agrosilvopasture-tech.2025.4.2.189