Ekstraksi Dan Karakterisasi Kitosan Dari Kulit Udang Windu (Penaeus monodon) Serta Proses Depolimerisasi Kitosan Dengan Hidrogen Peroksida Berdasarkan Variasi Suhu Pemanasan

Extraction and Characterization of Chitosan From Windu Shrimp Shell (Penaeus monodon) and Depolymerization Chitosan Process With Hydrogen Peroxide Based On Heating Temperature Variations

  • Matheis F.J.D.P. Tanasale Department of Chemistry, Faculty of Mathematics and Natural Science, University of Pattimura-Indonesia
  • Ivonne Telussa Department of Chemistry, Faculty of Mathematics and Natural Science, University of Pattimura-Indonesia
  • Serly J. Sekewael Department of Chemistry, Faculty of Mathematics and Natural Science, University of Pattimura-Indonesia
DOI: https://doi.org/10.30598/ijcr.2016.3-mat
Keywords: Chitosan, depolymerization, heating temperature, hydrogen peroxide, oligochitosan

Abstract

An extraction of chitin from shell of the tiger shrimp (Penaeus monodon), a convertion chitin into chitosan and depolymerization chitosan into oligochitosan using hydrogen peroxide based on variations in heating temperature have been done. Chitosan had depolymerized and it’s molecular weight had tested by end group analysis method and it’s degree of deacetylation had tested by UV-Vis spectrophotometry method. Oligochitosan had obtained from the conversion of chitin is isolated from the shell of tiger shrimp and from commercial chitin. The content of chitin obtained in tiger shrimp shells was 35.90% while the result of the conversion of commercial chitin into chitosan amounted to 62.33%.  Characterization of functional groups using FTIR spectrophotometry showed that the conversion of chitosan from chitin commercial have absorption bands of 3617.56 (OH), 3050.47 - 3127.63 (-NH stretching), 2894.24 (-CH methylene), 1679.06 (-C = O), 1564.30 (-NH bending), and 1076.30 cm-1 (-CO-). The commercial chitosan which is characterized by FTIR spectrophotometric method also supports the results of the conversion of chitosan from chitin commercial.  In the process of depolymerization of chitosan by hydrogen peroxide was found that the greater heating temperature was used, the smaller the percent yield and molecular weight of oligochitosan were at 40 oC, 50 oC, 60 oC and 70 oC gained weight average molecular oligochitosan were 1030.12 g/mol, 1019, 28 g/mol, 978.12 g/mol, and 908.82 g/mol, respectively

Downloads

Download data is not yet available.
Published
2016-01-31
How to Cite
(1)
Tanasale, M.; Telussa, I.; Sekewael, S. Ekstraksi Dan Karakterisasi Kitosan Dari Kulit Udang Windu (Penaeus Monodon) Serta Proses Depolimerisasi Kitosan Dengan Hidrogen Peroksida Berdasarkan Variasi Suhu Pemanasan. Indo. J. Chem. Res. 2016, 3, 308-318.
Issue
Vol 3 No 2 (2016): Edisi Bulan Januari (Edition For January)
Section
Short communication

Authors who publish with this journal agree to the following terms:

  1. Copyright on any article is retained by the author(s).
  2. The author grants the journal, the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgment of the work’s authorship and initial publication in this journal.
  3. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
  4. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.
  5. The article and any associated published material is distributed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.