SINTESIS DAN KARAKTERISASI ZEOLIT MORDENIT (MOR) SECARA HIDROTERMAL MENGGUNAKAN KAOLIN DAN ABU SEKAM PADI SEBAGAI SUMBER SILIKA
Keywords:
mordenit, kaolin, abu sekam padi, hidrotermal
Abstract
Sintesis dan karakterisasi mordenit telah dilakukan dari abu sekam padi dan kaolin sumber silika dan alumina. Mordenit berhasil disintesis dari kaolin dan abu sekam padi menggunakan metode hidrotermal. Penelitian ini bertujuan untuk mengkaji proses pembentukan mordenit yang disintesis dari bahan alam. Komposisi rasio molar 10 Na2O : 100 SiO2 : 2 Al2O3 : 1800 H2O. Sintesis dilakukan secara hidrotermal pada suhu 175 °C selama 24 jam. Kaolin dan abu sekam padi langsung digunakan tanpa perlakuan lebih lanjut. Mordenit yang diperoleh dikarakterisasi dengan metode difraksi sinar-X (XRD).
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References
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[9] C. Covarrubias, R. García, R. Arriagada, J. Yánez, and M. T. Garland, “Cr(III) exchange on zeolites obtained from kaolin and natural mordenite,” Microporous Mesoporous Mater., vol. 88, no. 1, pp. 220–231, 2006, doi: https://doi.org/10.1016/j.micromeso.2005.09.007.
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[11] E. B. G. Johnson and S. E. Arshad, “Hydrothermally synthesized zeolites based on kaolinite: A review,” Appl. Clay Sci., vol. 97–98, pp. 215–221, 2014, doi: https://doi.org/10.1016/j.clay.2014.06.005.
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[15] E.-P. Ng, H. Awala, K.-H. Tan, F. Adam, R. Retoux, and S. Mintova, “EMT-type zeolite nanocrystals synthesized from rice husk,” Microporous Mesoporous Mater., vol. 204, pp. 204–209, 2015, doi: https://doi.org/10.1016/j.micromeso.2014.11.017.
[16] P. Cubillas and M. W. Anderson, “Synthesis Mechanism: Crystal Growth and Nucleation,” Zeolites and Catalysis. pp. 1–55, 21-Apr-2010, doi: https://doi.org/10.1002/9783527630295.ch1.
[17] D. Wu, B. Zhang, L. Yan, H. Kong, and X. Wang, “Effect of some additives on synthesis of zeolite from coal fly ash,” Int. J. Miner. Process., vol. 80, no. 2, pp. 266–272, 2006, doi: https://doi.org/10.1016/j.minpro.2006.05.005.
[18] J. de C. Izidoro, D. A. Fungaro, J. E. Abbott, and S. Wang, “Synthesis of zeolites X and A from fly ashes for cadmium and zinc removal from aqueous solutions in single and binary ion systems,” Fuel, vol. 103, pp. 827–834, 2013, doi: https://doi.org/10.1016/j.fuel.2012.07.060.
[19] X. Zhang, D. Tang, and G. Jiang, “Synthesis of zeolite NaA at room temperature: The effect of synthesis parameters on crystal size and its size distribution,” Adv. Powder Technol., vol. 24, no. 3, pp. 689–696, 2013, doi: https://doi.org/10.1016/j.apt.2012.12.010.
[20] B. J. Schoeman, J. Sterte, and J.-E. Otterstedt, “Colloidal zeolite suspensions,” Zeolites, vol. 14, no. 2, pp. 110–116, 1994, doi: https://doi.org/10.1016/0144-2449(94)90004-3.
[21] H. Liu, S. Peng, L. Shu, T. Chen, T. Bao, and R. L. Frost, “Magnetic zeolite NaA: Synthesis, characterization based on metakaolin and its application for the removal of Cu2+, Pb2+,” Chemosphere, vol. 91, no. 11, pp. 1539–1546, 2013, doi: https://doi.org/10.1016/j.chemosphere.2012.12.038.
[22] M. A. Klunk et al., “Synthesis and characterization of mordenite zeolite from metakaolin and rice husk ash as a source of aluminium and silicon,” Chem. Pap., vol. 74, no. 8, pp. 2481–2489, 2020, doi: 10.1007/s11696-020-01095-4.
Published
2022-01-31
How to Cite
Setyaningsih, S., & Dewanti, B. (2022). SINTESIS DAN KARAKTERISASI ZEOLIT MORDENIT (MOR) SECARA HIDROTERMAL MENGGUNAKAN KAOLIN DAN ABU SEKAM PADI SEBAGAI SUMBER SILIKA. Molluca Journal of Chemistry Education (MJoCE), 12(1), 23-32. https://doi.org/10.30598/MJoCEvol12iss1pp23-32
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