PRODUCTION OF ACTIVATED CARBON OF PALMYRA PALM FRUIT SHELL (Borassus flabellifer Linn.) FROM KISAR ISLAND, SOUTHWEST MALUKU REGENCY FOR ADSORPTION OF METHYL RED DYE

Ingrid Natasya Tritama Maromon; Yeslia Utubira; Romelos Untailawan

doi:10.30598/MJoCEvol13iss1pp56-63

Ingrid Natasya Tritama Maromon Universitas Pattimura
Yeslia Utubira Universitas Pattimura
Romelos Untailawan Universitas Pattimura

DOI: https://doi.org/10.30598/MJoCEvol13iss1pp56-63

Keywords: Activated Carbon, Palmyra Palm Shell, Methyl Red, Adsorption

Abstract

Palmyra palm is a species of palmae that grows a lot on Kisar Island where all parts of the plant can be utilized. However, the palmyra palm fruit shell has not been used and that is only thrown away. In this study, palmyra palm fruit shell were made as activated carbon and were characterized using XRD to determine the crystallinity properties of the palmyra palm fruit shell activated carbon and adsorption test was carried out to determine the capacity and efficiency of activated carbon adsorption to methyl red dye. The production of palmyra palm fruit shell activated carbon is carried out through the carbonization stage at 300°C for 1 hour, and followed by chemical activation using H₃PO₄10% solution for 24 hours. The results of the analysis using XRD showed that the activated carbon of the palmyra palm fruit shell formed peaks with the highest intensity at diffraction angles of 2θ = 26.5241° and 27.6274° with d-spacing values (Å) = 3.36059 and 3.22884, which are characteristic peaks of carbon and are amorphous. The adsorption of methyl red 20 ppm use batch method, with various contact times of 5, 10, 15, 20, 25, and 30 minutes. The results of showed that on 15 minutes was the optimal time, with 0.25 gram mass of the adsorbent and the adsorption capacity and adsorption efficiency was 0.87 mg/g and 44.3%, respectively.

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References

Agusdin, A., & Setiorini, I. A. 2020. Analisa Kemampuan Penyerapan Bubur Kertas (Pulp) dari Kertas Bekas Sebagai Adsorben Zat Warna Reaktif dan Logam Berat (Cu Dan Fe) Dari Limbah Cair Tekstil dengan Adsorber Vertikal. Jurnal Teknik Patra Akademika, 11(01), 4-12.
Ahmad, M. A., Ahmad, N., & Bello, O. S. 2015. Modified durian seed as adsorbent for the removal of methyl red dye from aqueous solutions. Applied Water Science, 5(4), 407-423.
Akinola, L. K., & Umar, A. M. 2015. Adsorption of crystal violet onto adsorbents derived from agricultural wastes: kinetic and equilibrium studies. Journal of Applied Sciences and Environmental Management, 19(2), 279-288.
Anggraeni, I. S., & Yuliana, L. E. 2015. Pembuatan karbon aktif dari limbah tempurung siwalan (Borassus flabellifer L.) dengan menggunakan aktivator seng klorida (ZnCl2) dan natrium karbonat (Na2CO3). Doctoral dissertation, Institut Teknologi Sepuluh Nopember.
Asrijal, A., Chadijah, S., & Aisyah, A. 2014. Variasi konsentrasi aktivator Asam Sulfat (H2SO4) pada karbon aktif ampas tebu terhadap kapasitas adsorpsi logam Timbal. Al-Kimia, 2(1), 33-44.
Dim, P. E. 2013. Adsorption of methyl red and methyl orange using different tree bark powder. Adsorption, 4(1), 330-338.
Goa, A. A., Gauru, I., Solo, A. A. M., & Mere, J. K. 2014. Pembuatan Filter Ganda Mangan-Zeolit dan Arang Aktif Tempurung Lontar Asal NTT Untuk Menurunkan Kadar Logam Fe dan Mn dalam Limbah Cucian Mangan di Desa Noebesa Kabupaten Timor Tengah Selatan. In Prosiding Seminar Nasional Sains dan Teknik (Sainstek) UNDANA.
Fuadah, S. R., & Rahmayanti, M. 2019. Adsorpsi-Desorpsi Zat Warna Naftol Blue Black Menggunakan Adsorben Humin Hasil Isolasi Tanah Gambut Riau, Sumatera. Analit: Analytical and Environmental Chemistry, 4(2), 59-67.
Ihsan, F. 2022. Pemanfaatan limbah tempurung siwalan (Borassus flabelifer L.) sebagai karbon aktif dengan aktivator ZnCl2 dan Na2CO3 untuk penjernihan minyak jelantah. Doctoral dissertation, Universitas Islam Negeri Maulana Malik Ibrahim.
Isiuku, B. O., & Onyema, M. O. 2017. Batch Removal of Metanil Yellow (MY) from Aqueous Solution by Adsorption on HNO3-Treated-H3PO4-Activated Carbon (NATPAAC) from Gmelina arborea Roxb.: Kinetic and Mechanism Studies. World News of Natural Sciences, 13, 10-26.
Jacob, S. K. 2021. Adsorpsi Ion Pb2+ Secara Kolom Menggunakan Karbon Aktif Kulit Kayu Kesambi. Skripsi. Universitas Pattimura, Ambon.
Kayadoe, V., Sunarti, S., Utubira, Y., & Kayadoe, N. 2020. Preparasi dan Karakterisasi Arang dari Ampas Sagu Sebagai Adsorben dalam Menurunkan Kadar COD dan BOD Limbah Batik Cair Pabrik Tahu. Molluca Journal of Chemistry Education (MJoCE), 10(2), 81-88.
Khuluk, R. H., & Rahmat, A. 2019. Removal of methylene blue by adsorption onto activated carbon from coconut shell (Cocous nucifera L.). Indonesian Journal of Science & Technology, 4(2), 229-240.
Kurniawan, I. K. G. I., & Sutapa, J. G. 2012. Pembuatan dan Pemanfaatan Arang aktif dari tempurung buah lontar (Borrasus flabellifer Linn) Sebagai Absorben Limbah Batik Kayu. Yogyakarta: Fakultas Kehutanan, UGM.
Laksono, E. W. 2009. Kajian penggunaan adsorben sebagai alternatif pengolahan limbah zat pewarna tekstil. In Prosiding Seminar Nasional Kimia FMIPA UNY.
Lestari, D. D. 2020. Kinetika Adsorpsi Metil Oranye Pada Adsorben Karbon Aktif Dari Cangkang Ketapang (Terminalia Catappa). Doctoral Dissertation, Universitas Muhammadiyah Palembang.
Nitsae, M., Lano, L. A., & Ledo, M. E. 2020. Pembuatan Arang Aktif dari Tempurung Siwalan (Borassus flabellifer L.) yang Diaktivasi dengan Kalium Hidroksida (KOH). Biota: Jurnal Ilmiah Ilmu-Ilmu Hayati, 5(1), 8-15.
Nurkholifa, A. 2019. Pembuatan Karbon Aktif dari Ampas Sagu Sebagai Adsorben Logam Fe dalam Limbah Laboratorium Kimia. Skripsi. Universitas pattimura, Ambon.
Permatasari, I., Nugroho, R. A., & Meitiniarti, V. I. 2018. Dekolorisasi pewarna tekstil sumifix blue dan reactive red 2 oleh mikroba yang diisolasi dari limbah industri tekstil. Jurnal Bioteknologi dan Biosains Indonesia, 5(1), 20-26.
Purnama, H., & Kurnianto, A. R. 2016. Pemanfaatan tongkol jagung untuk adsorpsi zat warna Reactive Blue 19. Fakultas Teknik, Prodi Teknik Kimia, Universitas Muhammadiyah Surakarta.
Rachmawati, V., Nurjayati, R., & Yuniati, M. D. 2022. Penurunan Konsentrasi COD Limbah Batik Pada Proses Seeding dan Aklimatisasi Menggunakan Material Preservasi Mikroorganisme (MPMO). Jurnal Kesehatan Lingkungan Indonesia, 21(1), 73-82.
Sahusilawane, A. M., Uluputty, M. R., Kembauw, E., & Djoko, S. W. 2018. Hapa: a Local Wisdom of Meher Ethnic Group on Kisar Island to Ensure Food Security. Jurnal Penelitian Kesejahteraan Sosial, 14(3), 305-316.
Santhi, T., Manonmani, S., & Smitha, T. 2010. Removal of methyl red from aqueous solution by activated carbon prepared from the Annona squmosa seed by adsorption. Chemical engineering research bulletin, 14(1), 11-18.
Solihudin, S., Rustaman, R., & Haryono, H. 2020. Pembentukan Karbon Konduktif dari Sekam Padi dengan Metode Hidrotermal Menggunakan Larutan Kalium Karbonat. Chimica et Natura Acta, 8(1), 42-49.
Yuan, N., Cai, H., Liu, T., Huang, Q., & Zhag, X. 2019. Adsorptive removal of methylene blue from aqueous solution using coal fly ash-derived mesoporous silica material. Adsorption Science & Technology, 37(3-4), 333-348.